专利名称:CATALYTIC SYSTEMS OF THE ZIEGLER-NATTA TYPE AND METHOD FORPRODUCTION THEREOF
发明人:FOETTINGER, KLAUS,FUNK, GUIDO,KOELLE,
PETER,WULFF-DOERING, JOACHIM
申请号:EP01987773.7申请日:20011018公开号:EP1326899A2公开日:20030716
摘要:A method for production of catalytic systems of the Ziegler-Natta type ischaracterised in comprising the following steps: A) bringing an inorganic metal oxide anda magnesium compound of formula MgRnX2-n into contact, where X = independently,fluorine, chlorine, bromine, iodine, hydrogen, NR2, OR, SR, SO3R or OC(O)R and R =independently, C1-C20 linear, branched, or cyclic alkyl, a C2-C10 alkenyl, an alkylaryl with1-10 C atoms in the alkyl group and 6-20 C atoms in the aryl group, or a C6-C18 aryl andn =1 or 2, then, B) bringing the intermediate product obtained in step A) into contact witha halogenating reagent, C) bringing the intermediate product obtained in step B) intocontact with a) a tetravalent titanium compound, b) a metallo-organic compound ofgroup 3 of the periodic system and c) optionally, an electron-donor compound and D)washing the product obtained in step C) with an aprotic solvent. The invention furtherrelates to a catalytic system obtained as above and a method for the polymerisation ofolefins.
申请人:BASELL POLYOLEFINE GMBH
地址:Brühler Strasse 50389 Wesseling DE
国籍:DE
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